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CwppwbeQ0Rzvx-NCO32- + 2H+ = CO2! + H2O D"l'lSnmReQ0Rzkxx-NOH- +H+ = H2O 25 NRlcknxv/f AN2vid\(ϑ:N28 g B17 g NH3vir(vϑ/f1 mol C18 g H2O(WhQrQ NvSOy/f22.4 L D\40 g NaOHnN1 L4l-N @b_nm-NNaOHvir(vϑSm^:N1 mol/L 26 NR gsQir((uvl-N cknxv/f `$Cl2S(uN6R o}v| a$SiS(uN6R JS[SOPge b$SiO2S(uN6R IQ[~~ AS g`$a$ BS ga$b$ CS g`$b$ Dcknx 27 NRx(WNё^\SuS^e vQ-NSbNCQ }vSTN NOSuSSv/f Azkxx Bz]xx CSmkxx DSm]xx 28 NR gsQir(Rybc~elvS-N Ncknxv/f A(uR|Sx4l-Nvx B(uvel\eg4l6Rb4l C(un0ǏnvelRy]xxTlP[ D(uRpvelRy/lST/lSVSO 29 NRS^-N N^\NRbS^v/f AYNpN"llS^6RSYNp B2upN/llS^6RSN/l2up CYNpN/lS"lS^6RS/lYNp DYNpOnvV/lSxnm*r 30(Wؚ)n0ؚSTPSBRagN Nv[핹[hV-N ۏLS^N2(g)+3H2(g) EMBED ChemWindow.Document 2NH3(g) NR gsQl Ncknxv/f A0Rs^ae ckS^sI{NS^s BX'Y"llvSm^SX'YS^s C(W NagN N "llhQlS:N(ll D0Rs^ae SO|-NTir(vSm^ NQ9eS ,{a!wS^ b qQ40R laNy1.T{wSMR\[\~QvTyQ[kXQnZi0 2.(u݄0ўrX4l{bWs{\T{HhvcT{(Wv^vMOn0 SNN;`R;`RNRpec:y,{a!wSR:N_T{T T{0_T{Sb 0Sf[1 0_O 0Sf[2 0_O !jWW :N@b gu_T{ T{Sb 0Sf[Nu;m 0 O1 0 0ir(~gN'`( 0 O3 $N*N!jWWTR{Q[ u9hnc O!jWW bvQN\OT{0 _RċwSNN0_T{,gSb2*N\ qQ20R 318R ܔNSmkxxSuS^vSf[e z_:NCu+2 H2SO4(Sm) % CuSO4+ SO2! + 2 H2O vQ-NܔCQ }vSTN kX GSؚ b MNO kX 'lS b ؏S N T SmH2SO4\O BR(WS^-N 傈mN0.5 mol Cu RhQrQ NubSO2vSOy~:N L0 3212R ]wA0B0C0D0EGW:N-Nf[Sf[-N8^ir( (WN[agN NvNlSsQ|Y NV@b:yS^agNTRNir]weu 0  `$A8^)n N:NĞ~rvlSOUS(0 a$B:NNy8^SNё^\US( (WQvSmkxx-NOS0 b$Cv4lnm/fNye'lx NCv~b-N+T gNAv TvCQ }0 VT{ (1) AvSf[_:N gb^ё^\US(AvCQ }vgؚckSTN:N CvSf[_:N 0 (2)AN4lS^vSf[e z_:N 0 (3)ANES^ubDvyP[e z_:N 0 (4)(WEv4lnm-NReQϑ"l'lSnm ‰[0Rvsa:N 0 N0 T{u9hnc Ov!jWW T{ O 0Sf[Nu;m 0 O1 !jWWvuT{N O 0ir(~gN'`( 0 O3 vuT{N 0N 0N T20R0 _RċwSNN O 0Sf[Nu;m 0 O1 !jWWvu\OT{ ,gSb4*N\ qQ20R 33(3R) NRlcknxv/f kX^S 0 `$NSO;N/feEQnir( 4l1\ NeEQN0 a$x'`ߘircv1\/fTwegkxvir(0 b$xT/fNSO_{v_ϑCQ }0 c$:NNOߘir wwegfoN TeS2bkSOW EeߘTmRBRT2PBRSNYRp0 34(4R) Nh/fgTLrQzP[Sň NvRf0 T0 T QzP[RMe`$\| a$*s b$}v܃ c$ߘvO(g(W 18!sX-NOX[12*NguNeg\S Nh@bRMe-N [+Tˆ}v(v/f kX^S N T [+Tm|v/f [+T~u }v/f ^\NsTBRv/f 0 35(8R)ObsX0Tt)R(uDn]b:NN{|qQ Tvvh0$Re NRl/f&TcknxkX " b  0 (1)4lSOv[%{QS g)RN'YYpe4luR iirvu0 (2)Q\:gRf>\lc>e/f9eU'Yl(ϑv͑ce0 (3)qp^_QXeONu g[lSO ['Yl balg0 (4)\W>WR{|v^V6e)R(u &{TSc~SU\vBl0 36(5R)]w20 g NaOHN100 mLzvxp`}Y[hQS^ VT{ (1)QQNaOHNvxS^vSf[e z_0 (2)20 g NaOHvir(vϑ/fY\ (3)zvx-NHClvir(vϑSm^/fY\ _RċwSNN O 0ir(~gN'`( 0 O3 !jWWvu\OT{ ,gSb4*N\ qQ20R 33(4R) (1) NRCQ }SP[v5uP[c^Vcknxv/f 0 A   B   C    D   (2)gCQ }vyr_5uP[c^_:Nnsnnpn+2 CQ }SP[vgY5uP[B\ Nvb[5uP[[ g [0 (3)9hncNB\5uP[[Net $ReSO3RP[vzSOgW:N___________0 (4)`$r^Qa$vfSOExb$/lS NyvfSOvqp1uNO0Rؚvz^:N (kX^S)0 34(6R)X0Y0Z0W/fCQ }hTghMRVhTg-NvVy8^CQ } vQvsQOo`Y Nh CQ }vsQOo`XXvW`SP[8hY3*N~ N g5uP[ Nk*N~ Nv5uP[pevI{Y8^)n8^S N YUS(/fmĞrVSO 8^(Wkpq\USDяlyZZTY ThTg Zv5u'`'YNYWWvNy8h }v(ϑpe:N63 -NP[pe:N34(1)YMONCQ }hTgh-N,{ NhTg,{000e0 (2)YTZvgؚN'lSir[^v4lSirvx'`:_v/f0000QSf[_ 0 (3)XO2RP[-NX[(W000*N. RP[/f________(kX g'` b ^g'` )RP[0 (4)WvW`SP[8hY5uP[c^_/f000000000000 35(5R).l/f0Wt Ng:N0N[vCQ }0 (1)QQW`.lSP[vN5uP[c^_/f_________________0 (2)NH4+NCH4N:NI{5uP[SO RNH4+vzzgW:N 0 (3)_kxxܔnm-NReQǏϑ(l4l Subm݄rv[Cu(NH3)4]2 MyP[ vQ-NCu2 NNH3KNvSf[./f 0 (4)Cu NN3 b_bvvfSO~gvvfހYSV@b:y0RvfSO-NN TN*NN3-(}vt)'}vCu (\ўt) g______*N0 365R s gNyܔ|Tݔ|vmTir7hT0:NKm[7hT-Nݔv+Tϑ yS5.0 gdk7hTnN%b_t-N \100 mLzvxReQvQ-Np`}Y[hQS^ iRYOVSO2.3 g0 (1)mTir-Nݔv(ϑRpe:NY\ (2)@b(uvx-Nn(vir(vϑSm^:NY\ V]wnfؚ-Nf[N4ls^Ջ7h Sf[7hST{Hh ,{`!wS b qQ60R b,gSb30\ k\2R qQ60R k\S gN*N y&{Ta 1A 2D 3D 4A 5D 6A 7C 8B 9D 10C 11C 12B 13A 14D 15D 16D 17B 18C 19B 20D 21C 22A 23C 24D 25B 26D 27A 28A 29B 30C ,{a!wS^ b qQ20R N0_T{,gSb2*N\ qQ20R 318R GSؚ 'lS 'lS 11.2L 3212R (1) Cl2 +7 HCl (2) Cl2 + H2O = HCl + HClO (3)2Fe2++ Cl2 =2Fe3++ 2 Cl- (4) g}vrn}rlmub 6qTŏSbpp~r gTSb~rlm0 N0 T{u9hnc Ov!jWW T{ O 0Sf[Nu;m 0 O1 !jWWvuT{N O 0ir(~gN'`( 0 O3 vuT{N 0N 0N T20R0 N O 0Sf[Nu;m 0 O1 !jWWvu\OT{ ,gSb4*N\ qQ20R 33(3R)b$ 34(4R) a$ `$ b$ c$ (kzz1R) 35(8R)1 2 " 3 " 4 " (kzz2R) 36(5R)(1)NaOH+HCl=NaCl+H2O (2R) (2) n(NaOH) EMBED Equation.3 0.5mol (1R) (3) c(HCl) EMBED Equation.3 5mol/L (2R) N O 0ir(~gN'`( 0 O3 !jWWvu\OT{ ,gSb4*N\ qQ20R 33(4R) (1)D (2)2 (3)s^b(ck) N҉b_ (4)`$b$a$ (kzz1R) 34(6R) (1) VIA (2) HClO4 (3)2 ^g'` (4)1s22s22p63s23p63d104s1b[Ar]3d104s1 (,{(4)\2R vQYOkzz1R) 35(5R) (1)2s22p3 (2)ckVbSO (3)MMO.(bqQN.) 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